Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/109698
Title: | catena-Poly[[(1,10-phenanthroline-κ(2) N,N')copper(II)]-μ-2,2'-iminodibenzoato-κ(4) O,O':O'',O'''] | Authors: | Yuste-Vivas, Consuelo Coutinho, Joana T Pereira, Laura C. J. Silva, Manuela Ramos |
Keywords: | single-crystal X-ray study; T = 293 K; mean (C–C) = 0.005 A°; R factor = 0.035; wR factor = 0.089; data-to-parameter ratio = 13.0 | Issue Date: | 1-May-2013 | Publisher: | International Union of Crystallography | Project: | This work was supported by the Fundo Europeu de Desenvolvimento Regional-QREN-Compete through projects PTDC/FIS/102284/2008 and PEst-C/FIS/UI0036/2011 – Fundac¸a˜o para a Cieˆ ncia e Tecnologia (FCT). | Serial title, monograph or event: | Acta Crystallographica Section E: Structure Reports Online | Volume: | 69 | Issue: | Pt 5 | Abstract: | The structure of the title compound, [Cu(C14H9NO4)(C12H8N2)] n , consists of zigzag polymeric chains along the c axis. The asymmetric unit contains one Cu(II) atom which is coordinated by one 2,2'-imino-dibenzoate ligand and a one phenanthroline unit. Two intra-molecular N-H⋯O hydrogen bonds occur. The supra-molecular structure is characterized by weak C-H⋯O hydrogen bonds and π-π stacking inter-actions, forming a three-dimensional supramolecular network. The shortest centroid-centroid distances between neighbouring phenanthroline aromatic rings and 2,2'-imino-dibenzoate rings are 3.684 (1) and 3.640 Å, respectively. The shortest intra-chain Cu⋯Cu distance is 7.2885 (9) and the shortest Cu⋯Cu distance between Cu atoms in different chains is 7.1103 (6) Å. | URI: | https://hdl.handle.net/10316/109698 | ISSN: | 1600-5368 | DOI: | 10.1107/S1600536813009203 | Rights: | openAccess |
Appears in Collections: | FCTUC Física - Artigos em Revistas Internacionais |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
CatenaPoly110phenanthrolinesup2sup-NNcopperII-22iminodibenzoatosup4sup-OO-OOActa-Crystallographica-Section-E-Structure-Reports-Online.pdf | 606.75 kB | Adobe PDF | View/Open |
Page view(s)
54
checked on Sep 25, 2024
Download(s)
24
checked on Sep 25, 2024
Google ScholarTM
Check
Altmetric
Altmetric
This item is licensed under a Creative Commons License